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Though I have yet to 100% everything myself, it seems to be that you have battle every piece available, use all potions, ethers, gain all treasure chests and summons, even ones locked away in special areas, and even fight 'rare battle pieces' spawned.

In addition I've found you also need to gain every 'reward' from destiny points available, so that once the rewards at the top all read as PP rewards, you should be done.

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